Supramolecular structures are generated from manganese thiodiacetate (tda) units and substituted bipyridine (bipy) ligands (see pictures). Analysis of the π-stacking and DFT calculations for isolated binuclear units suggest that, in some cases, the geometry of the building blocks depends ultimately on the strength of noncovalent interactions between the 1D coordination polymers.
Supramolecular interactions as determining factors of the geometry of metallic building blocks: Tetracarboxylate dimanganese species / Grirrane, A.; Pastor, A.; Galindo, A.; DEL RO, D.; Orlandini, A.; Mealli, C.; Ienco, A.; Caneschi, Andrea; FERNANDEZ SANZ, J.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 44:(2005), pp. 3429-3432. [10.1002/anie.200462965]
Supramolecular interactions as determining factors of the geometry of metallic building blocks: Tetracarboxylate dimanganese species
CANESCHI, ANDREA;
2005
Abstract
Supramolecular structures are generated from manganese thiodiacetate (tda) units and substituted bipyridine (bipy) ligands (see pictures). Analysis of the π-stacking and DFT calculations for isolated binuclear units suggest that, in some cases, the geometry of the building blocks depends ultimately on the strength of noncovalent interactions between the 1D coordination polymers.
| File | Dimensione | Formato | |
|---|---|---|---|
|
AngewChemInterEd_2005.pdf
Accesso chiuso
Descrizione: AngewChemInterEd_2005
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Tutti i diritti riservati
Dimensione
349.2 kB
Formato
Adobe PDF
|
349.2 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
