A practical synthesis of N-benzyl-N-glycosylhydroxylamines 3 (R = CH2Ph) is reported. The ability of these compounds to act as versatile synthetic intermediates is demonstrated by their oxidation followed by cycloaddition to N-glcosyl isoxazolidines and by the novel direct cycloaddition as masked acyclic. highly functionalized chiral nitrones
Practical Synthesis of N-Alkyl-N-glycosylhydroxylamines, Multitalented Precursors of Enantiomerically Pure Nitrones / S. CICCHI; M. CORSI; M. MARRADI; A. GOTI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 43:(2002), pp. 2741-2743. [10.1016/S0040-4039(02)00372-6]
Practical Synthesis of N-Alkyl-N-glycosylhydroxylamines, Multitalented Precursors of Enantiomerically Pure Nitrones
CICCHI, STEFANO;M. MARRADI;GOTI, ANDREA
2002
Abstract
A practical synthesis of N-benzyl-N-glycosylhydroxylamines 3 (R = CH2Ph) is reported. The ability of these compounds to act as versatile synthetic intermediates is demonstrated by their oxidation followed by cycloaddition to N-glcosyl isoxazolidines and by the novel direct cycloaddition as masked acyclic. highly functionalized chiral nitrones
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