Mixed systems contg. fluorocarbons (FC) phase sep. below certain temps. The liq.-liq. coexistence curves show upper crit. soln. temps. (Tc) that depend on the nature of the components. In this work, we report the phase sepn. measurements of mixts. obtained from short-chain linear perfluoroalkanes (perfluorohexane, perfluoroheptane, and perfluorooctane) with some n-alkanes, cyclohexane, benzene, ethers, and chlorinated solvents. The results are discussed in terms of the chem. nature and polarizability of the components.
Phase Separation in Binary Mixtures Containing Linear Perfluoroalkanes / LO NOSTRO, Pierandrea; Scalise, L.; Baglioni, Piero. - In: JOURNAL OF CHEMICAL AND ENGINEERING DATA. - ISSN 0021-9568. - STAMPA. - 50:(2005), pp. 1148-1152. [10.1021/je049620w]
Phase Separation in Binary Mixtures Containing Linear Perfluoroalkanes
LO NOSTRO, PIERANDREA;BAGLIONI, PIERO
2005
Abstract
Mixed systems contg. fluorocarbons (FC) phase sep. below certain temps. The liq.-liq. coexistence curves show upper crit. soln. temps. (Tc) that depend on the nature of the components. In this work, we report the phase sepn. measurements of mixts. obtained from short-chain linear perfluoroalkanes (perfluorohexane, perfluoroheptane, and perfluorooctane) with some n-alkanes, cyclohexane, benzene, ethers, and chlorinated solvents. The results are discussed in terms of the chem. nature and polarizability of the components.
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