The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.

Methyltrioxorhenium Catalyzed Domino Epoxidation-Nucleophilic Ring Opening of Glycals / G. SOLDAINI; F. CARDONA; A. GOTI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 44:(2003), pp. 5589-5592. [10.1016/S0040-4039(03)01386-8]

Methyltrioxorhenium Catalyzed Domino Epoxidation-Nucleophilic Ring Opening of Glycals

CARDONA, FRANCESCA;GOTI, ANDREA
2003

Abstract

The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.
2003
44
5589
5592
G. SOLDAINI; F. CARDONA; A. GOTI
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/251399
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