The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.
Methyltrioxorhenium Catalyzed Domino Epoxidation-Nucleophilic Ring Opening of Glycals / G. SOLDAINI; F. CARDONA; A. GOTI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 44:(2003), pp. 5589-5592. [10.1016/S0040-4039(03)01386-8]
Methyltrioxorhenium Catalyzed Domino Epoxidation-Nucleophilic Ring Opening of Glycals
CARDONA, FRANCESCA;GOTI, ANDREA
2003
Abstract
The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.File in questo prodotto:
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