The first successful catalytic oxidation procedure for the chemoselective conversion of imines to nitrones is reported. The reaction is general, high yielding, and user and environmentally friendly, and furnishes a solution to the yet unanswered issue of regioselective access to nitrones by oxidation of nitrogen derivatives.
Catalytic Oxidation of Imines to Nitrones Based on Methyltrioxorhenium/Urea Hydrogen Peroxide: A mild and easy chemo- and regioselective entry to nitrones / G. SOLDAINI; F. CARDONA; A. GOTI. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 9:(2007), pp. 473-476. [10.1021/ol062862w]
Catalytic Oxidation of Imines to Nitrones Based on Methyltrioxorhenium/Urea Hydrogen Peroxide: A mild and easy chemo- and regioselective entry to nitrones
SOLDAINI, GIANLUCA;CARDONA, FRANCESCA;GOTI, ANDREA
2007
Abstract
The first successful catalytic oxidation procedure for the chemoselective conversion of imines to nitrones is reported. The reaction is general, high yielding, and user and environmentally friendly, and furnishes a solution to the yet unanswered issue of regioselective access to nitrones by oxidation of nitrogen derivatives.
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