LiNTf2 in the reaction of lactones with amines is able to activate cyclic esters towards ring opening, thus leading to clean open-chain amides under mild conditions and using a stoichiometric amount of amine. The generality of the method was demonstrated by a range of selected lactones and amines.
LiNTf2-Catalyzed aminolysis of lactones with stoichiometric quantities of amines / Lalli, C.; Trabocchi, Andrea; Menchi, Gloria; Guarna, Antonio. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - --:(2008), pp. 189-192. [10.1055/s-2007-1000882]
LiNTf2-Catalyzed aminolysis of lactones with stoichiometric quantities of amines
TRABOCCHI, ANDREA;MENCHI, GLORIA;GUARNA, ANTONIO
2008
Abstract
LiNTf2 in the reaction of lactones with amines is able to activate cyclic esters towards ring opening, thus leading to clean open-chain amides under mild conditions and using a stoichiometric amount of amine. The generality of the method was demonstrated by a range of selected lactones and amines.
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