The first catalytic oxidation of aryl oximes to nitro compounds by means of methyltrioxorhenium and urea hydroperoxide is reported. The formation of carbamates, probably occurring through formation of nitrile oxide intermediates, has been observed from 2,6-disubstituted aryl oximes.
Methyltrioxorhenium Catalyzed Oxidation of Aromatic Aldoximes / F. CARDONA; G. SOLDAINI; A. GOTI. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - 2004:(2004), pp. 1553-1556. [10.1055/s-2004-829088]
Methyltrioxorhenium Catalyzed Oxidation of Aromatic Aldoximes
CARDONA, FRANCESCA;GOTI, ANDREA
2004
Abstract
The first catalytic oxidation of aryl oximes to nitro compounds by means of methyltrioxorhenium and urea hydroperoxide is reported. The formation of carbamates, probably occurring through formation of nitrile oxide intermediates, has been observed from 2,6-disubstituted aryl oximes.File in questo prodotto:
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