A novel single-molecule magnet of the Mn-12 family, [Mn12O12(O2CC6H5)(8)(L)(4)(H2O)(4)].8CH(2)Cl(2), has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2-), which leads to selective occupation of axial binding sites.
Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn-12 core: a route to the controlled functionalisation of single-molecule magnets / M. PACCHIONI; A. CORNIA; A. C. FABRETTI; L. ZOBBI; D. BONACCHI; A. CANESCHI; G. CHASTANET; D. GATTESCHI; R. SESSOLI. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 22:(2004), pp. 2604-2605. [10.1039/b411320a]
Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn-12 core: a route to the controlled functionalisation of single-molecule magnets
CANESCHI, ANDREA;GATTESCHI, DANTE;SESSOLI, ROBERTA
2004
Abstract
A novel single-molecule magnet of the Mn-12 family, [Mn12O12(O2CC6H5)(8)(L)(4)(H2O)(4)].8CH(2)Cl(2), has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2-), which leads to selective occupation of axial binding sites.
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