Macrocyclic molecules containing appropriate binding sites and cavities of suitable size and shape may be designed to form selective inclusion complexes. Actu- ally, the molecular topology of the host molecule can be synthetically modulated in order to bind many different chemical species. For this purpose, aza macrocyclic receptors able to bind different kinds of substrates, such as inorganic or organic cation or anionic specie have been studied to elaborate their use as selective host molecules, molecular carriers, and catalysts. We have therefore devised a synthetic procedure able to produce, in high yield, very large azamacrocycles
Synthetic route to produce Giant-Siaze azamacrocycles / C.Bazzicalupi; A.Bencini; V.Fusi; M.Micheloni; P.Paoletti; B.Valtancoli. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 59:(1994), pp. 7508-7510.
Synthetic route to produce Giant-Siaze azamacrocycles
BAZZICALUPI, CARLA;BENCINI, ANDREA;VALTANCOLI, BARBARA
1994
Abstract
Macrocyclic molecules containing appropriate binding sites and cavities of suitable size and shape may be designed to form selective inclusion complexes. Actu- ally, the molecular topology of the host molecule can be synthetically modulated in order to bind many different chemical species. For this purpose, aza macrocyclic receptors able to bind different kinds of substrates, such as inorganic or organic cation or anionic specie have been studied to elaborate their use as selective host molecules, molecular carriers, and catalysts. We have therefore devised a synthetic procedure able to produce, in high yield, very large azamacrocyclesI documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.