A novel and simple procedure for reduction of hydroxylamines to the corresponding amines by means of indium powder in aqueous media is reported. Applicability to one-pot reactions and isoxazolidine N-O bond reduction is also demonstrated. A catalytic version of the process using 2-5% In in the presence of other metals (Zn, Al) has been successfully developed.
Indium-Mediated Reduction of Hydroxylamines to Amines / S. CICCHI; M. BONANNI; F. CARDONA; J. REVUELTA; A. GOTI. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 5:(2003), pp. 1773-1776. [10.1021/ol034434l]
Indium-Mediated Reduction of Hydroxylamines to Amines
CICCHI, STEFANO;BONANNI, MARCO;CARDONA, FRANCESCA;GOTI, ANDREA
2003
Abstract
A novel and simple procedure for reduction of hydroxylamines to the corresponding amines by means of indium powder in aqueous media is reported. Applicability to one-pot reactions and isoxazolidine N-O bond reduction is also demonstrated. A catalytic version of the process using 2-5% In in the presence of other metals (Zn, Al) has been successfully developed.
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