The synthesis of three new tris-macrocycles, containing three [12]aneN4 (L1), [12]aneN3O (L2), or [14]- aneN4 (L3) moieties appended to a tren unit, is reported. The crystal structure of the [(Na(ClO4)6) ⊂L12H13]Na6Cl2- (ClO4)12 compound shows the anionic cluster [Na(ClO4)6]5- assembled inside the cavity defined by two bowl-shaped polyammonium receptors, held by multiple charge-charge and hydrogen bond interactions.
Synthesis of new tren-based tris-macrocycles. Anion cluster assembling inside the cavity generated by a bowl-shaped receptor / C.Bazzicalupi; A.Bencini; E.Berni; A.Bianchi; S.Ciattini; C.Giorgi; S. Maoggi; P.Paoletti; B.Valtancoli. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 67:(2002), pp. 9107-9110. [10.1021/jo020474b]
Synthesis of new tren-based tris-macrocycles. Anion cluster assembling inside the cavity generated by a bowl-shaped receptor.
BAZZICALUPI, CARLA;BENCINI, ANDREA
;BIANCHI, ANTONIO
;CIATTINI, SAMUELE;GIORGI, CLAUDIA
;PAOLETTI, PIERO;VALTANCOLI, BARBARA
2002
Abstract
The synthesis of three new tris-macrocycles, containing three [12]aneN4 (L1), [12]aneN3O (L2), or [14]- aneN4 (L3) moieties appended to a tren unit, is reported. The crystal structure of the [(Na(ClO4)6) ⊂L12H13]Na6Cl2- (ClO4)12 compound shows the anionic cluster [Na(ClO4)6]5- assembled inside the cavity defined by two bowl-shaped polyammonium receptors, held by multiple charge-charge and hydrogen bond interactions.File | Dimensione | Formato | |
---|---|---|---|
JOC-trismacro.pdf
Accesso chiuso
Descrizione: lavoro pubblicato
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Tutti i diritti riservati
Dimensione
165.8 kB
Formato
Adobe PDF
|
165.8 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.