2-Trimethylsilyl-substituted five-membered heterocycles can be accessed through the reaction of bromo(methoxy)methyltrimethylsilane with 1,2-dithiols, 1,2-mercapto alcohols, 1,2-mercapto amines, and 1,2-hydroxy amines, leading to the formation of several 2-silylated 1,3-dithiolanes, -oxathiolanes, - thiazolidines, and -oxazolidines.
General access to a novel class of silyl heterocycles / A. Degl'Innocenti; A. Capperucci; I. Malesci; M. Acciai; G. Castagnoli. - In: CHEMISTRY OF HETEROCYCLIC COMPOUNDS. - ISSN 0069-3154. - STAMPA. - 12:(2006), pp. 1838-1844.
General access to a novel class of silyl heterocycles
DEGL'INNOCENTI, ALESSANDRO;CAPPERUCCI, ANTONELLA;CASTAGNOLI, GIULIO
2006
Abstract
2-Trimethylsilyl-substituted five-membered heterocycles can be accessed through the reaction of bromo(methoxy)methyltrimethylsilane with 1,2-dithiols, 1,2-mercapto alcohols, 1,2-mercapto amines, and 1,2-hydroxy amines, leading to the formation of several 2-silylated 1,3-dithiolanes, -oxathiolanes, - thiazolidines, and -oxazolidines.
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