An X-ray structure of a Co(II) complex of bidentate chelating 2-acetyl-1,3-indandione (2AID) is reported-Co(2AID)2(H2O)2 2H2O. The compound crystallizes in the monoclinic space group P21/n with four molecules per unit cell. The molecular structure shows distorted octahedral geometry of the metal center. The complex is characterized by EPR and magnetic measurements, which show high-spin electronic structure for the metal ion.
X-ray structure and magnetochemical study on a Co(II) complex of 2-acetyl-1,3-indandione / A. Ahmedova; O. Cador; L. Sorace; S. Ciattini; D. Gatteschi; M. Mitewa. - In: JOURNAL OF COORDINATION CHEMISTRY. - ISSN 0095-8972. - STAMPA. - 61:(2008), pp. 3879-3886. [10.1080/00958970802187134]
X-ray structure and magnetochemical study on a Co(II) complex of 2-acetyl-1,3-indandione
SORACE, LORENZO;CIATTINI, SAMUELE;GATTESCHI, DANTE;
2008
Abstract
An X-ray structure of a Co(II) complex of bidentate chelating 2-acetyl-1,3-indandione (2AID) is reported-Co(2AID)2(H2O)2 2H2O. The compound crystallizes in the monoclinic space group P21/n with four molecules per unit cell. The molecular structure shows distorted octahedral geometry of the metal center. The complex is characterized by EPR and magnetic measurements, which show high-spin electronic structure for the metal ion.
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