Complementarity between different techniques (magnetization, HF-HFEPR, FDMRS) and angular-overlap-model calculations allow the precise determination of the spin-Hamiltonian parameters in an isolated octahedral NiII complex (see structure), which exhibits the largest easy axis magnetic anisotropy reported to date (D=−10.1 cm−1, E/|D|=0.02).
Very large ising-type magnetic anisotropy in a mononuclear Ni-II complex / G. Rogez; J. N. Rebilly; A. L. Barra; L. Sorace; G. Blondin; N. Kirchner; M. Duran; J. van Slageren; S. Parsons; L. Ricard; A. Marvilliers; T. Mallah. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 44:(2005), pp. 1876-1879. [10.1002/anie.200462294]
Very large ising-type magnetic anisotropy in a mononuclear Ni-II complex
SORACE, LORENZO;
2005
Abstract
Complementarity between different techniques (magnetization, HF-HFEPR, FDMRS) and angular-overlap-model calculations allow the precise determination of the spin-Hamiltonian parameters in an isolated octahedral NiII complex (see structure), which exhibits the largest easy axis magnetic anisotropy reported to date (D=−10.1 cm−1, E/|D|=0.02).File | Dimensione | Formato | |
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