A new eliminative rearrangement of p-silyl carbanions requires phenyl on carbon α- to silicon when the conjugate acid has a pKa (DMSO) in the range 12-30; rearrangement involves silicon and not phenyl migration
Elimination-Rearrangement in beta-Functionalised Silanes. The direction of the rearrangement and its scope / S. Menichetti; C. J. M. Stirling. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - STAMPA. - -:(1992), pp. 741-742. [10.1039/p29920000741]
Elimination-Rearrangement in beta-Functionalised Silanes. The direction of the rearrangement and its scope
MENICHETTI, STEFANO;
1992
Abstract
A new eliminative rearrangement of p-silyl carbanions requires phenyl on carbon α- to silicon when the conjugate acid has a pKa (DMSO) in the range 12-30; rearrangement involves silicon and not phenyl migration
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