Single crystal magnetic studies combined with a theoretical analysis show that cancellation of the magnetic moments in the trinuclear Dy(3+) cluster [Dy(3)(mu(3)-OH)(2)L(3)Cl(H(2)O)(5)]Cl(3), resulting in a nonmagnetic ground doublet, originates from the noncollinearity of the single-ion easy axes of magnetization of the Dy(3+) ions that lie in the plane of the triangle at 120 degrees one from each other. This gives rise to a peculiar chiral nature of the ground nonmagnetic doublet and to slow relaxation of the magnetization with abrupt accelerations at the crossings of the discrete energy levels.
Spin chirality in a molecular dysprosium triangle: The archetype of the noncollinear ising model / Luzon J; Bernot K; Hewitt IJ; C E. Anson; A K. Powell; R Sessoli. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - STAMPA. - 100:(2008), pp. 247205-1-247205-4.
Spin chirality in a molecular dysprosium triangle: The archetype of the noncollinear ising model
SESSOLI, ROBERTA
2008
Abstract
Single crystal magnetic studies combined with a theoretical analysis show that cancellation of the magnetic moments in the trinuclear Dy(3+) cluster [Dy(3)(mu(3)-OH)(2)L(3)Cl(H(2)O)(5)]Cl(3), resulting in a nonmagnetic ground doublet, originates from the noncollinearity of the single-ion easy axes of magnetization of the Dy(3+) ions that lie in the plane of the triangle at 120 degrees one from each other. This gives rise to a peculiar chiral nature of the ground nonmagnetic doublet and to slow relaxation of the magnetization with abrupt accelerations at the crossings of the discrete energy levels.File | Dimensione | Formato | |
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