Reaction of acyl chlorides with phenylselenotrimethyl-silane promoted by TBAF afforded a mild general access to selenolesters in good yields. When acyl chlorides were reacted with bis(trimethylsilyl)selenide (HMDSS) in 2:1 or 1:1 ratio a selective entry to selenoanhydrides or diacyl diselenides respectively was obtained.

Organoselenosilanes mediated selective mild access to selenolesters, selenoanhydrides and diacyl diselenides / A. Capperucci; A. Degl’Innocenti; C. Tiberi. - In: SYNLETT. - ISSN 0936-5214. - ELETTRONICO. - ..:(2011), pp. 2248-2252. [10.1055/s-0030-1261195]

Organoselenosilanes mediated selective mild access to selenolesters, selenoanhydrides and diacyl diselenides

CAPPERUCCI, ANTONELLA;DEGL'INNOCENTI, ALESSANDRO;TIBERI, CATERINA
2011

Abstract

Reaction of acyl chlorides with phenylselenotrimethyl-silane promoted by TBAF afforded a mild general access to selenolesters in good yields. When acyl chlorides were reacted with bis(trimethylsilyl)selenide (HMDSS) in 2:1 or 1:1 ratio a selective entry to selenoanhydrides or diacyl diselenides respectively was obtained.
2011
..
2248
2252
A. Capperucci; A. Degl’Innocenti; C. Tiberi
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/550274
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