A dinuclear Ni(II)–Zn(II) complex of 2-bis-(aminoethyl)-aminomethylphenol (L) was prepared by mixing the homodinuclear complexes of Ni(II) and Zn(II). The mixed hetero-dinuclear complex was characterized by X-ray analysis. Crystal data for the compound [NiZn(H-1L)2(H2O)2][ClO4]2 revealed that it is monoclinic; space group P21/n with a=20.137(2) A ˚ , b=9.480(1) A ˚ , c=15.934(1) A ˚ , b=100.45(1), V=2991.3(5) A ˚ 3, Z=4, R=0.094.
CRYSTAL STRUCTURE AND CHEMICAL PROPERTIES OF NI(II)-ZN(II) HETERO-DINUCLEAR COMPLEX / G. AMBROSI; P. DAPPORTO; M. FORMICA; V. FUSI; L. GIORGI; A. GUERRI; M. MICHELONI; P. PAOLI; P. ROSSI. - In: JOURNAL OF SUPRAMOLECULAR CHEMISTRY. - ISSN 1472-7862. - STAMPA. - 2:(2002), pp. 301-303. [10.1016/S1472-7862(03)00084-4]
CRYSTAL STRUCTURE AND CHEMICAL PROPERTIES OF NI(II)-ZN(II) HETERO-DINUCLEAR COMPLEX
DAPPORTO, PAOLO;GUERRI, ANNALISA;PAOLI, PAOLA;ROSSI, PATRIZIA
2002
Abstract
A dinuclear Ni(II)–Zn(II) complex of 2-bis-(aminoethyl)-aminomethylphenol (L) was prepared by mixing the homodinuclear complexes of Ni(II) and Zn(II). The mixed hetero-dinuclear complex was characterized by X-ray analysis. Crystal data for the compound [NiZn(H-1L)2(H2O)2][ClO4]2 revealed that it is monoclinic; space group P21/n with a=20.137(2) A ˚ , b=9.480(1) A ˚ , c=15.934(1) A ˚ , b=100.45(1), V=2991.3(5) A ˚ 3, Z=4, R=0.094.
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