The application of sequential Ti- / Cu-catalysis in the model one-pot synthesis of benzodiazepine(di)ones promoted by microwave irradiation demonstrates the expediency of dual catalysis in coupling-cyclization methods useful for applications to diversity-oriented synthesis.
One-pot sequential Ti- / Cu-catalysis for tandem amidation/Ullmann-type cyclization: synthesis of model benzodiazepine(di)ones promoted by microwave irradiation / L.Ciofi ; A.Trabocchi ; C.Lalli ; G.Menchi; A.Guarna. - In: ORGANIC & BIOMOLECULAR CHEMISTRY. - ISSN 1477-0520. - STAMPA. - 10:(2012), pp. 2780-2786. [10.1039/C2OB07063D]
One-pot sequential Ti- / Cu-catalysis for tandem amidation/Ullmann-type cyclization: synthesis of model benzodiazepine(di)ones promoted by microwave irradiation
CIOFI, LEONARDO;TRABOCCHI, ANDREA;MENCHI, GLORIA;GUARNA, ANTONIO
2012
Abstract
The application of sequential Ti- / Cu-catalysis in the model one-pot synthesis of benzodiazepine(di)ones promoted by microwave irradiation demonstrates the expediency of dual catalysis in coupling-cyclization methods useful for applications to diversity-oriented synthesis.
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