The complete matrices for ligand field spin-orbit coupling perturbations are provided for dl, d2, and d3 ions in CsU symmetry. The importance of using such matrices for the interpretation of the electronic properties of trigonal bipyramidal five-coordinated complexes is stressed, in contrast with previous uses in the literature of D3h matrices
Ligand field spin-orbit coupling calculations for d7, d8, d9 (d3, d2, d1) five coordinated complexes of C3v symmetry / A. Bencini;D. Gatteschi. - In: THE JOURNAL OF PHYSICAL CHEMISTRY. - ISSN 0022-3654. - STAMPA. - 80:(1976), pp. 2126-2132. [10.1021/j100560a015]
Ligand field spin-orbit coupling calculations for d7, d8, d9 (d3, d2, d1) five coordinated complexes of C3v symmetry
BENCINI, ALESSANDRO;GATTESCHI, DANTE
1976
Abstract
The complete matrices for ligand field spin-orbit coupling perturbations are provided for dl, d2, and d3 ions in CsU symmetry. The importance of using such matrices for the interpretation of the electronic properties of trigonal bipyramidal five-coordinated complexes is stressed, in contrast with previous uses in the literature of D3h matrices
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