Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers
Iodine activation of coordinated white phosphorus: formation and transformation of 1,3-dihydride-2-iodidecyclotetraphosphane / Barbaro, P.; Bazzicalupi, C.; Peruzzini, M.; Seniori Costantini, S.; Stoppioni, P.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 51:(2012), pp. 8628-8631. [10.1002/anie.201203908]
Iodine activation of coordinated white phosphorus: formation and transformation of 1,3-dihydride-2-iodidecyclotetraphosphane
BAZZICALUPI, CARLA;STOPPIONI, PIERO
2012
Abstract
Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers
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