The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent β, the self-diffusion constant D, the average translational relaxation time ⟨τ⟩, and the temperature dependence of confinement radius α extracted from the elastic fraction of immobile water molecules p(Q) were obtained from the analyses of the low-Q spectra according to the relaxing cage model. Measurements were made using C-S-H of three different water contents, 10%, 17%, and 30%. Among the three samples of C-S-H gel with different water contents, the values of β decrease with increasing water contents, while α increases. The values of D and ⟨τ⟩ are insensitive to temperature for the two lower water contents, as opposed to the 30% case where a slight variation is observed. The trend for violation of the Stokes-Einstein relation is only visible in the case of 30% water content.
Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation / Hua Li;Emiliano Fratini;Wei-Shan Chiang;Piero Baglioni;Eugene Mamontov;Sow-Hsin Chen. - In: PHYSICAL REVIEW E, STATISTICAL, NONLINEAR, AND SOFT MATTER PHYSICS. - ISSN 1539-3755. - STAMPA. - 86:(2012), pp. 1-7. [10.1103/PhysRevE.86.061505]
Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation
FRATINI, EMILIANO;BAGLIONI, PIERO;
2012
Abstract
The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent β, the self-diffusion constant D, the average translational relaxation time ⟨τ⟩, and the temperature dependence of confinement radius α extracted from the elastic fraction of immobile water molecules p(Q) were obtained from the analyses of the low-Q spectra according to the relaxing cage model. Measurements were made using C-S-H of three different water contents, 10%, 17%, and 30%. Among the three samples of C-S-H gel with different water contents, the values of β decrease with increasing water contents, while α increases. The values of D and ⟨τ⟩ are insensitive to temperature for the two lower water contents, as opposed to the 30% case where a slight variation is observed. The trend for violation of the Stokes-Einstein relation is only visible in the case of 30% water content.File | Dimensione | Formato | |
---|---|---|---|
2012PRE_CSH.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
872.63 kB
Formato
Adobe PDF
|
872.63 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.