Molecular magnetism is here presented with emphasis concerning the single molecule magnets (SMMs). The architecture of SMMs is reviewed as well as the various ingredients promoting magnetic anisotropy and the relation between magnetic anisotropy and the dynamics of magnetization. Then it is shown how XAS and XMCD can be unique tools to unravel the magnetic properties of SMM submonolayers grafted on clean surfaces. We bring a special attention to the spectral features associated with the magnetic anisotropy and magnetization dynamics.
XAS and XMCD of Single Molecule MagnetsMagnetism and Synchrotron Radiation / Sessoli, R.; Mannini, M.; Pineider, F.; Cornia, A.; Sainctavit, Ph.. - STAMPA. - 133:(2010), pp. 279-311. (Intervento presentato al convegno 5th School on Magnetism and Synchrotron Radiation tenutosi a Mittelwihr, FRANCE nel OCT 19-24, 2008) [10.1007/978-3-642-04498-4_10].
XAS and XMCD of Single Molecule MagnetsMagnetism and Synchrotron Radiation
SESSOLI, ROBERTA;MANNINI, MATTEO;CORNIA, GIOVANNI ANDREA;
2010
Abstract
Molecular magnetism is here presented with emphasis concerning the single molecule magnets (SMMs). The architecture of SMMs is reviewed as well as the various ingredients promoting magnetic anisotropy and the relation between magnetic anisotropy and the dynamics of magnetization. Then it is shown how XAS and XMCD can be unique tools to unravel the magnetic properties of SMM submonolayers grafted on clean surfaces. We bring a special attention to the spectral features associated with the magnetic anisotropy and magnetization dynamics.
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