Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H2, PH3, H3PO2, H3PO4, and H3PO4 (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H2 generation.
High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation / Matteo Ceppatelli; Roberto Bini; Maria Caporali; Maurizio Peruzzini. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 52:(2013), pp. 2313-2317. [10.1002/anie.201208684]
High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation
CEPPATELLI, MATTEO;BINI, ROBERTO;
2013
Abstract
Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H2, PH3, H3PO2, H3PO4, and H3PO4 (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H2 generation.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
(102)Angew_P.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
2.63 MB
Formato
Adobe PDF
|
2.63 MB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
