Homogeneous catalysis is an efficient tool to carry out hydrogenation processes but the major drawback is represented by the separation of the expensive catalyst from the product mixture. In this view we prepared a polyester-based Pd catalytic systemthat offers the advantages of both homogenous and heterogeneous catalyses: efficacy, selectivity and recyclability. Here its application in the hydrogenation of selected a,a-unsaturated carbonyl compounds is described.
An easily recoverable and recyclable homogeneous polyester-based Pd catalytic system for the hydrogenation of α,β-unsaturated carbonyl compounds / Bartoli, Mattia; Rosi, Luca; Petrucci, Giorgio; Armelao, Lidia; Oberhauser, Werner; Frediani, Marco; Piccolo, Oreste; Rathod, Vikas Damu; Paganelli, Stefano. - In: CATALYSIS COMMUNICATIONS. - ISSN 1566-7367. - STAMPA. - 69:(2015), pp. 228-233. [10.1016/j.catcom.2015.07.002]
An easily recoverable and recyclable homogeneous polyester-based Pd catalytic system for the hydrogenation of α,β-unsaturated carbonyl compounds
BARTOLI, MATTIA;ROSI, LUCA;PETRUCCI, GIORGIO;FREDIANI, MARCO;
2015
Abstract
Homogeneous catalysis is an efficient tool to carry out hydrogenation processes but the major drawback is represented by the separation of the expensive catalyst from the product mixture. In this view we prepared a polyester-based Pd catalytic systemthat offers the advantages of both homogenous and heterogeneous catalyses: efficacy, selectivity and recyclability. Here its application in the hydrogenation of selected a,a-unsaturated carbonyl compounds is described.File | Dimensione | Formato | |
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