Aziridines react efficiently with bis(trimethyl)silyl-sulfide and -selenide to afford a direct access to -amino thiols and selenols. Synthesis of 2,4-disubstituted 1,3-selenazolidines is obtained through reaction of 1,2-amino selenols with aldehydes.
Aziridines ring opening by silyl chalcogenides: A stereoselective access to polyfunctionalized molecules as precursor of sulfurated and selenated heterocycles / Tanini, Damiano; Barchielli, Giulia; Benelli, Francesca; Deglinnocenti, Alessandro; Capperucci, Antonella. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - ELETTRONICO. - 190:(2015), pp. 1265-1270. [10.1080/10426507.2014.1002615]
Aziridines ring opening by silyl chalcogenides: A stereoselective access to polyfunctionalized molecules as precursor of sulfurated and selenated heterocycles
TANINI, DAMIANO;DEGL'INNOCENTI, ALESSANDRO;CAPPERUCCI, ANTONELLA
2015
Abstract
Aziridines react efficiently with bis(trimethyl)silyl-sulfide and -selenide to afford a direct access to -amino thiols and selenols. Synthesis of 2,4-disubstituted 1,3-selenazolidines is obtained through reaction of 1,2-amino selenols with aldehydes.
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