The reaction of the chromium(III) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3 center dot CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium-dysprosium complex. Magnetic investigations revealed that the new 3d-4f complex exhibits single molecule magnet behaviour.
Single molecule magnet behaviour in a rare trinuclear Cr<sup>III</sup>Dy<sup>III</sup><inf>2</inf> methoxo-bridged complex / Car, Pierre-Emmanuel; Favre, Annaïck; Caneschi, Andrea; Sessoli, Roberta. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - 44:(2015), pp. 15769-15773. [10.1039/c5dt02459e]
Single molecule magnet behaviour in a rare trinuclear CrIIIDyIII2 methoxo-bridged complex
CAR, PIERRE-EMMANUEL;FAVRE, ANNAICK;CANESCHI, ANDREA;SESSOLI, ROBERTA
2015
Abstract
The reaction of the chromium(III) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3 center dot CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium-dysprosium complex. Magnetic investigations revealed that the new 3d-4f complex exhibits single molecule magnet behaviour.
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