Compound [Cr-5(tpda)(4)Cl-2] (H(2)tpda = N-2, N-6-di(pyridin-2-yl)pyridine-2,6- diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr-2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.
Magnetic blocking in extended metal atom chains: A pentachromium(II) complex behaving as a single-molecule magnet / Cornia, A; Rigamonti, L.; Boccedi, S.; Clérac, R.; Rouzières, M.; Sorace, L.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 50:(2014), pp. 15191-15194. [10.1039/c4cc06693f]
Magnetic blocking in extended metal atom chains: A pentachromium(II) complex behaving as a single-molecule magnet
SORACE, LORENZO
2014
Abstract
Compound [Cr-5(tpda)(4)Cl-2] (H(2)tpda = N-2, N-6-di(pyridin-2-yl)pyridine-2,6- diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr-2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.
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