A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal–organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H–13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves.
Dynamic nuclear polarization enhanced solid-state NMR spectroscopy of functionalized metal-organic frameworks / Rossini, A.J., Zagdoun, A., Lelli, M., Canivet, J., Aguado, S., Ouari, O., Tordo, P., Rosay, M., Maas, W.E., Copéret, C., Farrusseng, D., Emsley, L., Lesage, A.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 51:(2012), pp. 123-127. [10.1002/anie.201106030]
Dynamic nuclear polarization enhanced solid-state NMR spectroscopy of functionalized metal-organic frameworks
LELLI, MORENOWriting – Review & Editing
;
2012
Abstract
A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal–organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H–13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves.
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