Stoichiometric copper(I) tetrakis(acetonitrile) is found to activate the thermal ring-closure reaction of a series of high-energy vinylheptafulvene isomers to the corresponding low-energy and photoactive dihydroazulenes, allowing the release of energy upon request.
An effective trigger for energy release of vinylheptafulvene-based solar heat batteries / Martina, Cacciarini; Alexandru, Vlasceanu; Martyn, Jevric; Mogens, Brøndsted Nielsen. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - (2017), pp. 5874-5877. [10.1039/C7CC01050H]
An effective trigger for energy release of vinylheptafulvene-based solar heat batteries
Martina, Cacciarini;
2017
Abstract
Stoichiometric copper(I) tetrakis(acetonitrile) is found to activate the thermal ring-closure reaction of a series of high-energy vinylheptafulvene isomers to the corresponding low-energy and photoactive dihydroazulenes, allowing the release of energy upon request.
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