End-off bicompartmental ligands bearing a nitronyl-nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p-4f, 2p-3d, and 2p-3d-4f complexes. The magnetic properties of the 2p-4f and 2p-3d-4f complexes have been investigated and rationalized by theoretical calculations.

A chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands / Patrascu, Andrei A.; Calancea, Sergiu; Briganti, Matteo; Soriano, Stã©phane; Madalan, Augustin M.; Cassaro, Rafael A. Allã£o; Caneschi, Andrea; Totti, Federico; Vaz, Maria G. F.; Andruh, Marius. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 53:(2017), pp. 6504-6507. [10.1039/c7cc03236f]

A chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

BRIGANTI, MATTEO;CANESCHI, ANDREA;TOTTI, FEDERICO;
2017

Abstract

End-off bicompartmental ligands bearing a nitronyl-nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p-4f, 2p-3d, and 2p-3d-4f complexes. The magnetic properties of the 2p-4f and 2p-3d-4f complexes have been investigated and rationalized by theoretical calculations.
2017
53
6504
6507
Patrascu, Andrei A.; Calancea, Sergiu; Briganti, Matteo; Soriano, Stã©phane; Madalan, Augustin M.; Cassaro, Rafael A. Allã£o; Caneschi, Andrea; Totti, Federico; Vaz, Maria G. F.; Andruh, Marius
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1099292
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