The complexation between 2-ureido-4[1H]-pyrimidinone (UPy) and 2,7-diamido-1,8-naphthyridine (NaPy) is used to promote the mild chemisorption of a UPy-functionalized terbium(III) double decker system on a silicon surface. The adopted strategy allows the single-molecule magnet behavior of the system to be maintained unaltered on the surface.
Self-Assembly of TbPc2 Single-Molecule Magnets on Surface through Multiple Hydrogen Bonding / Pedrini, Alessandro; Poggini, Lorenzo; Tudisco, Cristina; Torelli, Martina; Giuffrida, Antonino E; Bertani, Federico; Cimatti, Irene; Otero, Edwige; Ohresser, Philippe; Sainctavit, Philippe; Suman, Michele; Condorelli, Guglielmo G; Mannini, Matteo; Dalcanale, Enrico. - In: SMALL. - ISSN 1613-6810. - ELETTRONICO. - (2018), pp. 1702572-1702578. [10.1002/smll.201702572]
Self-Assembly of TbPc2 Single-Molecule Magnets on Surface through Multiple Hydrogen Bonding
Poggini, Lorenzo;Cimatti, Irene;Mannini, Matteo
;Dalcanale, Enrico
2018
Abstract
The complexation between 2-ureido-4[1H]-pyrimidinone (UPy) and 2,7-diamido-1,8-naphthyridine (NaPy) is used to promote the mild chemisorption of a UPy-functionalized terbium(III) double decker system on a silicon surface. The adopted strategy allows the single-molecule magnet behavior of the system to be maintained unaltered on the surface.
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