The possibility to operate on magnetic materials through the application of electric rather than magnetic fields—promising faster, more compact and energy efficient circuits—continues to spur the investigation of magnetoelectric effects. Symmetry considerations, in particular the lack of an inversion centre, characterize the magnetoelectric effect. In addition, spin–orbit coupling is generally considered necessary to make a spin system sensitive to a charge distribution. However, a magnetoelectric effect not relying on spin–orbit coupling is appealing for spin-based quantum technologies. Here, we report the detection of a magnetoelectric effect that we attribute to an electric field modulation of the magnetic exchange interaction without atomic displacement. The effect is visible in electron paramagnetic resonance absorption of molecular helices under electric field modulation and confirmed by specific symmetry properties and spectral simulation.

Electric field modulation of magnetic exchange in molecular helices / Fittipaldi M.; Cini A.; Annino G.; Vindigni A.; Caneschi A.; Sessoli R.. - In: NATURE MATERIALS. - ISSN 1476-1122. - ELETTRONICO. - 18:(2019), pp. 329-334. [10.1038/s41563-019-0288-5]

Electric field modulation of magnetic exchange in molecular helices

Fittipaldi M.;Caneschi A.;Sessoli R.
2019

Abstract

The possibility to operate on magnetic materials through the application of electric rather than magnetic fields—promising faster, more compact and energy efficient circuits—continues to spur the investigation of magnetoelectric effects. Symmetry considerations, in particular the lack of an inversion centre, characterize the magnetoelectric effect. In addition, spin–orbit coupling is generally considered necessary to make a spin system sensitive to a charge distribution. However, a magnetoelectric effect not relying on spin–orbit coupling is appealing for spin-based quantum technologies. Here, we report the detection of a magnetoelectric effect that we attribute to an electric field modulation of the magnetic exchange interaction without atomic displacement. The effect is visible in electron paramagnetic resonance absorption of molecular helices under electric field modulation and confirmed by specific symmetry properties and spectral simulation.
2019
18
329
334
Fittipaldi M.; Cini A.; Annino G.; Vindigni A.; Caneschi A.; Sessoli R.
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1167934
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