The synthesis of a bipyridine poly(lactic acid) carboxylic end-capped macroligand coordinated to a platinum center was reported. The reaction between the metal ion and the polymeric ligand was run in a very efficient way through a one-step synthesis and the complex was tested for selective hydrogenation of α,β-carbonyl compounds. High selectivity was proven for double bond hydrogenation of 2-cyclohexen-1-one (up to 99%) and the production of 1-butanol from (E)-but-2-enal. Moreover, the catalytic system was still active after three catalytic cycles

Catalytic performances of platinum containing PLLA macrocomplex in the hydrogenation of α, β -unsaturated carbonyl compounds / Bartoli M.; Rosi L.; Mini B.; Petrucci G.; Passaglia E.; Frediani M.. - In: APPLIED SCIENCES. - ISSN 2076-3417. - ELETTRONICO. - 9:(2019), pp. 3243-3252. [10.3390/app9163243]

Catalytic performances of platinum containing PLLA macrocomplex in the hydrogenation of α, β -unsaturated carbonyl compounds

BARTOLI, MATTIA
Conceptualization
;
Rosi L.
Conceptualization
;
PETRUCCI, GIORGIO;PASSAGLIA, ELISA;Frediani M.
Conceptualization
2019

Abstract

The synthesis of a bipyridine poly(lactic acid) carboxylic end-capped macroligand coordinated to a platinum center was reported. The reaction between the metal ion and the polymeric ligand was run in a very efficient way through a one-step synthesis and the complex was tested for selective hydrogenation of α,β-carbonyl compounds. High selectivity was proven for double bond hydrogenation of 2-cyclohexen-1-one (up to 99%) and the production of 1-butanol from (E)-but-2-enal. Moreover, the catalytic system was still active after three catalytic cycles
2019
9
3243
3252
Bartoli M.; Rosi L.; Mini B.; Petrucci G.; Passaglia E.; Frediani M.
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1171625
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