Symmetrical ditocopheryl disulfides (Toc)2S2 and symmetrical and unsymmetrical ditocopheryl sulfides (Toc)2S were simply prepared under remarkably mild conditions with complete control of the regiochemistry by using d-, g-, and b-tocopheryl-N-thiophthalimides (Toc-NSPht) as common starting materials. The roles of sulfur atom(s), Hbond and aryl ring substitution pattern on the antioxidant profile of these new compounds, which were assembled by linking together two tocopheryl units, are also discussed

Ditocopheryl Sulfides and Disulfides: Synthesis and Antioxidant Profile / Viglianisi C.; Vasa K.; Tanini D.; Capperucci A.; Amorati R.; Valgimigli L.; Baschieri A.; Menichetti S.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 25:(2019), pp. 9108-9116. [10.1002/chem.201901537]

Ditocopheryl Sulfides and Disulfides: Synthesis and Antioxidant Profile

Viglianisi C.;VASA, KRISTIAN;Tanini D.;Capperucci A.;Menichetti S.
2019

Abstract

Symmetrical ditocopheryl disulfides (Toc)2S2 and symmetrical and unsymmetrical ditocopheryl sulfides (Toc)2S were simply prepared under remarkably mild conditions with complete control of the regiochemistry by using d-, g-, and b-tocopheryl-N-thiophthalimides (Toc-NSPht) as common starting materials. The roles of sulfur atom(s), Hbond and aryl ring substitution pattern on the antioxidant profile of these new compounds, which were assembled by linking together two tocopheryl units, are also discussed
2019
25
9108
9116
Viglianisi C.; Vasa K.; Tanini D.; Capperucci A.; Amorati R.; Valgimigli L.; Baschieri A.; Menichetti S.
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1172396
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