Introducing Highly Redox‐Active Atomic Centers into Insertion‐Type Electrodes for Lithium‐Ion Batteries

The development of alternative anode materials with higher volumetric and gravimetric capacity allowing for fast delithiation and, even more important, lithiation is crucial for next-generation lithium-ion batteries. Herein, the development of a completely new active material is reported, which follows an insertion-type lithiation mechanism, metal-doped CeO  . Remarkably, the introduction of carefully selected dopants, herein exemplified for iron, results in an increase of the achievable capacity by more than %, originating from the reduction of the dopant to the metallic state and additional space for the lithium ion insertion due to a significant o-centering of the dopant atoms in the crystal structure, away from the original Ce site. In addition to the out- standing performance of such materials in high-power lithium-ion full-cells, the selective reduction of the iron dopant under preservation of the crystal structure of the host material is expected to open up a new field of research.