Compounds with the fresnoite structure type possess remarkable chemical diversity and a range of unique physical properties, including nonlinear optical (NLO) activity. K2Sb- (P2O7)F, which was reported recently, belongs to this group and its structure is not novel in terms of either the topology or local coordination geometry around the Sb3+ cations. The crystallographic disorder observed in the fresnoite-type structures can be explained by twinning, which is frequent for noncentrosymmetric crystals.
Correspondence on “K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance” / S. Krivovichev, L. Bindi. - In: ANGEWANDTE CHEMIE. - ISSN 0044-8249. - STAMPA. - 60:(2021), pp. 3854-3855.
Correspondence on “K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance”
L. BindiMembro del Collaboration Group
2021
Abstract
Compounds with the fresnoite structure type possess remarkable chemical diversity and a range of unique physical properties, including nonlinear optical (NLO) activity. K2Sb- (P2O7)F, which was reported recently, belongs to this group and its structure is not novel in terms of either the topology or local coordination geometry around the Sb3+ cations. The crystallographic disorder observed in the fresnoite-type structures can be explained by twinning, which is frequent for noncentrosymmetric crystals.
| File | Dimensione | Formato | |
|---|---|---|---|
|
Cariro Pentagonal fresnoite.pdf
Accesso chiuso
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Tutti i diritti riservati
Dimensione
513.08 kB
Formato
Adobe PDF
|
513.08 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
