A series of thia-bridged triarylamine[4]helicene-functionalized polynorbornenes P1, P2, and P3 were synthesized via ring-opening metathesis polymerization (ROMP). The polymers obtained undergo a reversible one-electron oxidation, in both solution and solid state, responding to the pH changes in the surrounding medium showing a clear reversible electrochromic behavior.

Thia-Bridged Triarylamine[4]helicene-Functionalized Polynorbor nenes as Redox-Active pH-Sensitive Polymers / Lupi M.; Menichetti S.; Stagnaro P.; Utzeri R.; Viglianisi C.. - In: SYNTHESIS. - ISSN 0039-7881. - ELETTRONICO. - 53:(2021), pp. 2602-2611. [10.1055/s-0040-1706743]

Thia-Bridged Triarylamine[4]helicene-Functionalized Polynorbor nenes as Redox-Active pH-Sensitive Polymers

Lupi M.;Menichetti S.;Viglianisi C.
2021

Abstract

A series of thia-bridged triarylamine[4]helicene-functionalized polynorbornenes P1, P2, and P3 were synthesized via ring-opening metathesis polymerization (ROMP). The polymers obtained undergo a reversible one-electron oxidation, in both solution and solid state, responding to the pH changes in the surrounding medium showing a clear reversible electrochromic behavior.
2021
SYNTHESIS
53
2602
2611
Lupi M.; Menichetti S.; Stagnaro P.; Utzeri R.; Viglianisi C.
1a - Articolo su rivista
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1245153
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