Potassium complexes are starting to gather more and more interest from academia and industry because of their intriguing application possibilities. Novel adducts of potassium hexafluoroacetylacetonato [K(hfa)] with polyethers (monoglyme, diglyme, triglyme, and tetraglyme) were synthesized through a single step reaction and characterized through FT-IR spectroscopy as well as 1H and 13C NMR spectroscopy. Single crystal X-ray diffraction studies enabled the identification of fascinating K coordination polymeric networks.
A One-Pot Synthesis of “K(hfa) glyme” Adducts: Effect of the Polyether Length on the Ion Coordination Sphere / Peddagopu N.; Sanzaro S.; Rossi P.; Paoli P.; Malandrino G.. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - STAMPA. - 2021:(2021), pp. 3776-3780. [10.1002/ejic.202100553]
A One-Pot Synthesis of “K(hfa) glyme” Adducts: Effect of the Polyether Length on the Ion Coordination Sphere
Rossi P.Membro del Collaboration Group
;Paoli P.Membro del Collaboration Group
;
2021
Abstract
Potassium complexes are starting to gather more and more interest from academia and industry because of their intriguing application possibilities. Novel adducts of potassium hexafluoroacetylacetonato [K(hfa)] with polyethers (monoglyme, diglyme, triglyme, and tetraglyme) were synthesized through a single step reaction and characterized through FT-IR spectroscopy as well as 1H and 13C NMR spectroscopy. Single crystal X-ray diffraction studies enabled the identification of fascinating K coordination polymeric networks.
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