A common criterion for designing performant single molecule magnets and pseudocontact shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex chemically designed to exhibit strong easy-axis type magnetic anisotropy that is preserved in dichloromethane solution at room temperature. Our detailed theoretical and experimental studies on the magnetic properties allowed explaining several features typical of highly performant SMMs. Moreover, the NMR characterization shows remarkably large chemical shifts, outperforming the current state-of-the art PCS tags.

A dysprosium single molecule magnet outperforming current pseudocontact shift agents / Santana, FS; Perfetti, M; Briganti, M; Sacco, F; Poneti, G; Ravera, E; Soares, JF; Sessoli, R. - In: CHEMICAL SCIENCE. - ISSN 2041-6520. - STAMPA. - 13:(2022), pp. 5860-5871. [10.1039/d2sc01619b]

A dysprosium single molecule magnet outperforming current pseudocontact shift agents

Perfetti, M;Briganti, M;Sacco, F;Ravera, E
;
Sessoli, R
2022

Abstract

A common criterion for designing performant single molecule magnets and pseudocontact shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex chemically designed to exhibit strong easy-axis type magnetic anisotropy that is preserved in dichloromethane solution at room temperature. Our detailed theoretical and experimental studies on the magnetic properties allowed explaining several features typical of highly performant SMMs. Moreover, the NMR characterization shows remarkably large chemical shifts, outperforming the current state-of-the art PCS tags.
2022
13
5860
5871
Santana, FS; Perfetti, M; Briganti, M; Sacco, F; Poneti, G; Ravera, E; Soares, JF; Sessoli, R
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1271040
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