The chemodivergent ring-opening of cyclobutanols is described under the carbocatalytic assistance of graphene oxide (GO). The protocol enables the synthesis of diversely functionalized dienes or indenes (26 examples) based on the amount of GO employed. Spectroscopic (XPS and ssNMR) as well as experimental investigations revealed a direct involvement of the π-domains of GO in tuning the stability of carbocationic intermediates during the reaction.

Graphene-Oxide Mediated Chemodivergent Ring-Opening of Cyclobutanols / Brunetti A.; Pintus A.; Lombardi L.; Kovtun A.; Mascietti F.; Bruno F.; Ravera E.; Melucci M.; Bertuzzi G.; Bandini M.. - In: CHINESE JOURNAL OF CHEMISTRY. - ISSN 1001-604X. - STAMPA. - 41:(2023), pp. 1333-1340. [10.1002/cjoc.202200757]

Graphene-Oxide Mediated Chemodivergent Ring-Opening of Cyclobutanols

Bruno F.;Ravera E.;
2023

Abstract

The chemodivergent ring-opening of cyclobutanols is described under the carbocatalytic assistance of graphene oxide (GO). The protocol enables the synthesis of diversely functionalized dienes or indenes (26 examples) based on the amount of GO employed. Spectroscopic (XPS and ssNMR) as well as experimental investigations revealed a direct involvement of the π-domains of GO in tuning the stability of carbocationic intermediates during the reaction.
2023
41
1333
1340
Brunetti A.; Pintus A.; Lombardi L.; Kovtun A.; Mascietti F.; Bruno F.; Ravera E.; Melucci M.; Bertuzzi G.; Bandini M.
File in questo prodotto:
File Dimensione Formato  
Chinese Journal of Chemistry - 2023 - Brunetti - Graphene‐Oxide Mediated Chemodivergent Ring‐Opening of Cyclobutanols.pdf

Accesso chiuso

Tipologia: Pdf editoriale (Version of record)
Licenza: Tutti i diritti riservati
Dimensione 2.26 MB
Formato Adobe PDF
2.26 MB Adobe PDF   Richiedi una copia

I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1310180
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 3
social impact