The metalloligand approach was used to obtain a novel CuII/ZnII heterobimetallic coordination polymer (CP) 1, based on the carefully designed bispidine ligand L4. CP 1, characterized by single crystal (SC-) and powder X-ray diffraction methods (P-XRD), is constituted by repeating large 32-membered macrocycles forming ribbon-like linear arrays and it features a CuII-coordination site occupied by a markedly labile MeCN. We also describe the synthesis and characterization of intermediate metalloligands (with CuII, FeIII, MnII, and PdII, the latter three obtained as SCs and characterized accordingly) and provide a view of potential intermediate species along the route from metalloligands to heterometallic CPs.

A Bispidine Based CuII/ZnII Heterobimetallic Coordination Polymer / Lippi, Martina; Wadepohl, Hubert; Comba, Peter; Cametti, Massimo. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - STAMPA. - 2022:(2022), pp. e202200221.e202200221-e202200221.e202200226. [10.1002/ejic.202200221]

A Bispidine Based CuII/ZnII Heterobimetallic Coordination Polymer

Lippi, Martina
Investigation
;
2022

Abstract

The metalloligand approach was used to obtain a novel CuII/ZnII heterobimetallic coordination polymer (CP) 1, based on the carefully designed bispidine ligand L4. CP 1, characterized by single crystal (SC-) and powder X-ray diffraction methods (P-XRD), is constituted by repeating large 32-membered macrocycles forming ribbon-like linear arrays and it features a CuII-coordination site occupied by a markedly labile MeCN. We also describe the synthesis and characterization of intermediate metalloligands (with CuII, FeIII, MnII, and PdII, the latter three obtained as SCs and characterized accordingly) and provide a view of potential intermediate species along the route from metalloligands to heterometallic CPs.
2022
2022
e202200221
e202200226
Lippi, Martina; Wadepohl, Hubert; Comba, Peter; Cametti, Massimo
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Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1349797
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