This work describes a straightforward approach to the production of highly-performing and costeffective C-based materials for energy storage application while proposing an original and effective method to the control of the final material morphology. Indeed, robust few-layer graphene-like and highly open-cell structures have been prepared by a modified chemical activation procedure starting from costless sugar/salt mixtures. The as-prepared C-samples ensure high ion-accessible surface area and low ion transport resistance, two key features for the fabrication of effective electrochemical double layer supercapacitors. A selected sample from this series exhibits high specific capacitance (Cg) (312 and 234 F g 1 at 0.5 and 50 A g 1 , respectively, in 0.5 M H2SO4), particularly at high current density values, along with excellent cycling stability and Cg retention for increasing chargeedischarge rates.
Tridimensional few-layer graphene-like structures from sugar-salt mixtures as high-performance supercapacitor electrodes / Ba H; Wang W; Tuci G; Pronkin SN; Weinberg C; Nguyen-Dinh L; Giambastiani G; Pham-Huu C. - In: MATERIALS TODAY ENERGY. - ISSN 2468-6069. - 10:(2018), pp. 118-125. [10.1016/j.mtener.2018.08.015]
Tridimensional few-layer graphene-like structures from sugar-salt mixtures as high-performance supercapacitor electrodes
Giambastiani G;
2018
Abstract
This work describes a straightforward approach to the production of highly-performing and costeffective C-based materials for energy storage application while proposing an original and effective method to the control of the final material morphology. Indeed, robust few-layer graphene-like and highly open-cell structures have been prepared by a modified chemical activation procedure starting from costless sugar/salt mixtures. The as-prepared C-samples ensure high ion-accessible surface area and low ion transport resistance, two key features for the fabrication of effective electrochemical double layer supercapacitors. A selected sample from this series exhibits high specific capacitance (Cg) (312 and 234 F g 1 at 0.5 and 50 A g 1 , respectively, in 0.5 M H2SO4), particularly at high current density values, along with excellent cycling stability and Cg retention for increasing chargeedischarge rates.File | Dimensione | Formato | |
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