On actiVation by MAO the CoII pyridinimine dichloride complex CoCl2N2 Ph catalyzes the unprecedented enchainment of one norbornene molecule with two ethylene molecules to giVe exo-2,exo-3 ethyl-Vinylnorbornane with high actiVity and complete diastereoselectivity.
Diastereoselective Alkyl-Vinylation of Norbornene Catalyzed by a Tetrahedral Pyridinimine Cobalt(II) Complex / Bianchini C; Giambastiani G; Meli A; Toti A. - In: ORGANOMETALLICS. - ISSN 0276-7333. - STAMPA. - 26:(2007), pp. 1303-1305. [10.1021/om070003l]
Diastereoselective Alkyl-Vinylation of Norbornene Catalyzed by a Tetrahedral Pyridinimine Cobalt(II) Complex
Giambastiani G;
2007
Abstract
On actiVation by MAO the CoII pyridinimine dichloride complex CoCl2N2 Ph catalyzes the unprecedented enchainment of one norbornene molecule with two ethylene molecules to giVe exo-2,exo-3 ethyl-Vinylnorbornane with high actiVity and complete diastereoselectivity.
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