A new molecular queuing process has been achieved, in which a single Pd-based catalytic system promotes two unrelated, sequential catalytic cycles in chronologically distinct order. This study demonstrates also that allylic alkylations can be catalyzed by the Herrmann’s phosphapalladacycle, a result that further supports the involvement of a Pd(0) species in its mechanism of action.
Pd(0)-catalyzed allylic alkylation/Heck coupling in domino sequence / Poli G; Giambastiani G; Pacini B. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 42:(2001), pp. 5179-5182. [10.1016/S0040-4039(01)00951-0]
Pd(0)-catalyzed allylic alkylation/Heck coupling in domino sequence
Giambastiani G;
2001
Abstract
A new molecular queuing process has been achieved, in which a single Pd-based catalytic system promotes two unrelated, sequential catalytic cycles in chronologically distinct order. This study demonstrates also that allylic alkylations can be catalyzed by the Herrmann’s phosphapalladacycle, a result that further supports the involvement of a Pd(0) species in its mechanism of action.
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