Magnetic Circular Dichroism Elucidates Molecular Interactions in Aggregated Chiral Organic Materials

Chiral materials formed by aggregated organic compounds play a fundamental role in chiral optoelectronics, photonics and spintronics. Nonetheless, a precise understanding of the molecular interactions involved remains an open problem. Here we introduce magnetic circular dichroism (MCD) as a new tool to elucidate molecular interactions and structural parameters of a supramolecular system. A detailed analysis of MCD together with electronic circular dichroism spectra combined to ab initio calculations unveils essential information on the geometry and energy levels of a self-assembled thin film made of a carbazole di-bithiophene chiral molecule. This approach can be extended to a generality of chiral organic materials and can help rationalizing the fundamental interactions leading to supramolecular order. This in turn could enable a better understanding of structure-property relationships, resulting in a more efficient material design.Magnetic circular dichroism gives access to the geometry and interactions leading to the supramolecular structure of a thin film of an organic chiral molecule. The technique presented here may be applied to elucidate the structures of aggregates of organic compounds.+image