The peculiar behavior of arsenoplatin-1, ([Pt(mu -NHC(CH3)O)(2)ClAs(OH)(2)], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named "AsPt blue". A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.
Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution / Cirri D.; Marzo T.; Mastrorilli P.; Petrelli V.; Todisco S.; De Giglio E.; Gellini C.; Ricci M.; Pratesi A.; Messori L.. - In: INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES. - ISSN 1422-0067. - ELETTRONICO. - 25:(2024), pp. 7408.0-7408.0. [10.3390/ijms25137408]
Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution
Cirri D.;Marzo T.;Gellini C.;Ricci M.;Messori L.
2024
Abstract
The peculiar behavior of arsenoplatin-1, ([Pt(mu -NHC(CH3)O)(2)ClAs(OH)(2)], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named "AsPt blue". A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.
| File | Dimensione | Formato | |
|---|---|---|---|
|
platino_blu24.pdf
accesso aperto
Tipologia:
Pdf editoriale (Version of record)
Licenza:
Open Access
Dimensione
911.77 kB
Formato
Adobe PDF
|
911.77 kB | Adobe PDF |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
