The peculiar behavior of arsenoplatin-1, ([Pt(mu -NHC(CH3)O)(2)ClAs(OH)(2)], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named "AsPt blue". A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.

Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution / Cirri D.; Marzo T.; Mastrorilli P.; Petrelli V.; Todisco S.; De Giglio E.; Gellini C.; Ricci M.; Pratesi A.; Messori L.. - In: INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES. - ISSN 1422-0067. - ELETTRONICO. - 25:(2024), pp. 7408.0-7408.0. [10.3390/ijms25137408]

Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution

Cirri D.;Marzo T.;Gellini C.;Ricci M.;Messori L.
2024

Abstract

The peculiar behavior of arsenoplatin-1, ([Pt(mu -NHC(CH3)O)(2)ClAs(OH)(2)], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named "AsPt blue". A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.
2024
25
0
0
Cirri D.; Marzo T.; Mastrorilli P.; Petrelli V.; Todisco S.; De Giglio E.; Gellini C.; Ricci M.; Pratesi A.; Messori L.
File in questo prodotto:
File Dimensione Formato  
platino_blu24.pdf

accesso aperto

Tipologia: Pdf editoriale (Version of record)
Licenza: Open Access
Dimensione 911.77 kB
Formato Adobe PDF
911.77 kB Adobe PDF

I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificatore per citare o creare un link a questa risorsa: https://hdl.handle.net/2158/1380152
Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 0
  • ???jsp.display-item.citation.isi??? 0
social impact