Attempts to synthesize a phenanthroline palladium(0) complex with an eta2 -coordinated nitrosoarene starting from a palladium(II) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(I) metallacyclic complexes that, on a closer inspection, were proven to be Pd(II) complexes with a new kind of radical-anionic nitrosoarene ligand.
A Non-Innocent Radical-Anionic Nitrosoarene Ligand Regularizes a Formal Palladium(I) Complex to Palladium(II) / Ramadan, D.R., Fouad, M.A., Ferretti, F., Brotons-Rufes, A., Macchi, P., Sorace, L., Gimferrer, M., Costabile, C., Ragaini, F.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - ELETTRONICO. - (2026), pp. 0-0. [10.1039/d6dt01038e]
A Non-Innocent Radical-Anionic Nitrosoarene Ligand Regularizes a Formal Palladium(I) Complex to Palladium(II)
Sorace, Lorenzo;
2026
Abstract
Attempts to synthesize a phenanthroline palladium(0) complex with an eta2 -coordinated nitrosoarene starting from a palladium(II) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(I) metallacyclic complexes that, on a closer inspection, were proven to be Pd(II) complexes with a new kind of radical-anionic nitrosoarene ligand.
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