A cluster of clusters: Two Y-and Yb-hydroxo/oxo clusters, encapsulated between two trivacant Wells-Dawson ligands, were prepared from carbonate-assisted hydrolysis. Carbonate also plays an important directing role in the formation of the wide range of bridging hydroxo units observed within the lanthanide-hydroxo/oxo cluster frameworks.
Polyoxometalate - Supported Y- and YbIII-Hydroxo/Oxo Clusters from Carbonate-Assisted Hydrolysis / FANG X; ANDERSON T. M; C. BENELLI; HILL C. L. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 11:(2005), pp. 712-718. [10.1002/chem.200400774]
Polyoxometalate - Supported Y- and YbIII-Hydroxo/Oxo Clusters from Carbonate-Assisted Hydrolysis
BENELLI, CRISTIANO;
2005
Abstract
A cluster of clusters: Two Y-and Yb-hydroxo/oxo clusters, encapsulated between two trivacant Wells-Dawson ligands, were prepared from carbonate-assisted hydrolysis. Carbonate also plays an important directing role in the formation of the wide range of bridging hydroxo units observed within the lanthanide-hydroxo/oxo cluster frameworks.File in questo prodotto:
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