SmI2 was used as reducing agent for the N–O bond cleavage in isoxazolidines. The procedure revealed is general and particularly useful for the transformation of 5-spirocyclopropane isoxazolidines to the corresponding beta-aminocyclopropanols, a troublesome transformation with other known reagents.
Samarium(II) iodide reduction of isoxazolidines / J. Revuelta; S. Cicchi; A. Brandi. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 45:(2004), pp. 8375-8377. [10.1016/j.tetlet.2004.09.050]
Samarium(II) iodide reduction of isoxazolidines
REVUELTA CRESPO, JULIA MARIA;CICCHI, STEFANO;BRANDI, ALBERTO
2004
Abstract
SmI2 was used as reducing agent for the N–O bond cleavage in isoxazolidines. The procedure revealed is general and particularly useful for the transformation of 5-spirocyclopropane isoxazolidines to the corresponding beta-aminocyclopropanols, a troublesome transformation with other known reagents.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
TL_2004_SmI.pdf
Accesso chiuso
Tipologia:
Versione finale referata (Postprint, Accepted manuscript)
Licenza:
Tutti i diritti riservati
Dimensione
263.23 kB
Formato
Adobe PDF
|
263.23 kB | Adobe PDF | Richiedi una copia |
I documenti in FLORE sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
